To limit the adverse effects of global warming, biofuels are currently one of the credible alternatives to fossil fuels whose consumption is a source of greenhouse gas emissions and environmental pollution with harmful effects. The present study aims to contribute to the fight against greenhouse gas emissions by converting wastes from rice cultivation in Kovié, Togo, into bioethanol. The hydrolysis of the rice waste was catalysed under heat and reflux with concentrated H2SO4 by varying the acid content from 0-10%. The pH of the hydrolysates and musts was measured with a pH meter. The variation of the concentration of the hydrolysates during the ethanolic fermentation reaction, carried out in Batch & Fed-Batch mode with the baker's yeast "Saccharomyces cerevisiae", was monitored by measuring the Brix degree using a refractometer. The bioethanol produced was purified by split distillation. The alcoholic strength of the distillates was determined by the pycnometric method, according to the guidelines of the Association of Official Analytical Chemists (AOAC).